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The present invention relates to new molecular sieve SSZ-71 prepared
using a N-benzyl-14-diazabicyclo[2.2.2]octane cation as a structure-directing
agent, methods for synthesizing SSZ-71 and processes employing SSZ-71
in a catalyst.
A crystalline material substantially free of framework phosphorus
and comprising a CHA framework type molecular sieve with stacking
faults or at least one intergrown phase of a CHA framework type
molecular sieve and an AEI framework type molecular sieve, wherein
said material, in its calcined, anhydrous form, has a composition
involving the molar relationship: (n)X.sub.2O.sub.3:YO.sub.2 wherein
X is a trivalent element; Y is a tetravalent element; and n is from
0 to about 0.5. The material exhibits activity and selectivity in
the conversion of methanol to lower olefins, especially ethylene
and propylene.
The invention relates to an aldehyde conversion method comprising
putting an aldehyde into contact with oxygenated water and with
a catalyst, under oxidation conditions, wherein the catalyst is
a molecular sieve with pores of a diameter of at least 0.52 nm and
has an empirical formula in a calcined and dehydrated form of (Sn.sub.xTi.sub.ySi.sub.1-x-y-zGe.sub.z)O.sub.2
wherein x is a molar fraction of the tin and has a value between
0.001 and 0.1; y is a molar fraction of titanium and has a value
from zero to 0.1; and z is the molar fraction molar of the germanium
and has a value from zero to 0.08.
The present invention relates to new crystalline molecular sieve
SSZ-70 prepared using a N,N'-diisopropyl imidazolium cation as a
structure-directing agent, methods for synthesizing SSZ-70 and processes
employing SSZ-70 in a catalyst.
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