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A process for synthesizing a high-silica aluminosilicate molecular
sieve, includes: subjecting, to hydrothermal synthesis, a raw material
containing Al, H, O and Si and, as other elements, at least Fe and
having a Si/Al molar ratio of 50 or more and a Si/Fe molar ratio
of 80 or less (45 or less when a high-silica aluminosilicate molecular
sieve having a .beta. type zeolite structure is produced) and then
subjecting the resulting material to heat treatment in an oxidizing
atmosphere at 300.degree. C. or more. The above process can synthesize
a high-silica zeolite low in Al content directly without dealumination
operation, and can provide process simplification and a higher yield.
The present invention relates to binder-free molecular sieve zeolite
granules of lithium zeolite A and lithium zeolite X, a process for
preparing these molecular sieve zeolite granules and their use for
preparing nitrogen or oxygen from air by pressure swing adsorption.
A process for modifying surfaces of zeolites and molecular sieve
membranes to decrease effective pore size for separation of materials
includes atomic layer controlled vapor or liquid deposition. The
atomic layer controlled deposition process steps include (i) exposing
the surface to a metal atom coordinated with ligand groups having
bonds that are hydrolyzable to form molecular bonded structures
on the surface, which structures comprise the metal atoms coordinated
with the ligand group or a modified ligand group and then (ii) hydrolyzing
the bonds and possibly, but not necessarily, cross-linking the bonds
in the ligand or modified ligand group.
A method for converting starting material to olefins comprising
contacting the starting material with a small pore non-zeolitic
molecular sieve catalyst under effective conditions to produce olefins,
wherein the non-zeolitic molecular sieve has been prepared in-situ
or modified after synthesis by incorporation using an alkaline earth
metal compound, wherein the alkaline earth metal ion is selected
from the group conisting of strontium, calcium, barium, and mixtures
thereof.
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